HuagongsheHuagongshe Chemistry Print Report · For research reference only
N,N-Dimethylaniline → 2-(Bis(4-(dimethylamino)phenyl)methyl)-5-(dimethylamino)benzoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N,N-Dimethylaniline | HCID 949 | — |
| Reactant | 1(3H)-Isobenzofuranone, 6-(dimethylamino)-3-[4-(dimethylamino)phenyl]- | HCID 93693 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Catalyst | Zincchloride | HCID 3007855 | — |
| Product | 2-(Bis(4-(dimethylamino)phenyl)methyl)-5-(dimethylamino)benzoic acid | HCID 102063 | — |
Reaction Steps
Proceeding in a manner similar to that described in part A above, but replacing the anhydrous zinc chloride with 9.3 g of anhydrous aluminum chloride, 70.0 ml of N,N-dimethylaniline and 14.9 g of 3-(4-dimethylaminophenyl)-6-dimethylaminophthalide, prepared as described in Example 1, part A above were interacted to obtain 16.1 g of 2-[4,4'-bis(dimethylamino)-benzhydryl]-5-dimethylaminobenzoic acid, a light blue powder which melted at 209°-213° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04595768 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-94e42cf5dd5344908659417591ba8fa9 |
| Source note | uspto-grants-1986_06 |