HCID 23025343, compound → HCID 86019636, compound

HRID 1983814Notes

Reaction equation

HRID 1983814 reaction equation
C([Sn](CCCC)(OCC(CC)CC)[O:6][Sn:7]([CH2:19][CH2:20][CH2:21][CH3:22])([CH2:15][CH2:16][CH2:17][CH3:18])[O:8][CH2:9][CH:10]([CH2:13][CH3:14])[CH2:11][CH3:12])CCC>O>[CH2:19]([Sn:7]([CH2:15][CH2:16][CH2:17][CH3:18])([O:6][CH2:9][CH:10]([CH2:13][CH3:14])[CH2:11][CH3:12])[O:8][CH2:9][CH:10]([CH2:11][CH3:12])[CH2:13][CH3:14])[CH2:20][CH2:21][CH3:22]

Participants

3

Reactant 1

HCID 23025343HCID 23025343, compound

Product 1

HCID 86019636HCID 86019636, compoundYield 94%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Nitrogen gas was fed from the gas supply line 7 at 0.04 NL/min, and a feed pump was used to start feeding from the supply line 4 a mixed solution of the starting material and the reactant prepared as described above at 20 g/Hr. The holding time in the reactor was about 32 minutes. Low boiling point substances, including water, began to be extracted in gaseous form from the extraction vent line 5 and high boiling point components began to flow out from the extraction line 6. Continuous feeding and continuous extraction operation was continued in this state for 2 hours. Analysis of the generated product extracted from the extraction line 6 showed that, using dibutyltin oxide as a reference, the generated product contained a dibutyltin alkoxide consisting of about a 94% yield of dibutyl-bis(2-ethyl-butyloxy)tin and about 6% of 1,1,3,3-tetrabutyl-1,3-bis(2-ethyl-butyloxy)-distannoxane. Tributyltin(2-ethyl-butyloxide) had a yield of 0.4%. Upon cooling of the gas phase extracted from the extraction vent line 5, a two-layer transparent liquid was obtained, in which moisture was present. The dehydration rate in the column reactor was 0.0033 mol/Hr, which was greater than the value 0.0005 mol/Hr calculated from expression (16).

Workup

  1. customthe reactant prepared
  2. extractionto be extracted in gaseous form from the extraction vent line 5 and high boiling point components
  3. waitcontinuous extraction operation was continued in this state for 2 hours
  4. extractionAnalysis of the generated product extracted from the extraction line 6

Sources & evidence

ORD record
ord-b5f5b0ed901e49a09e15c762091c59c3
Source dataset
uspto-grants-2009_06
Patent number
US07541482B2

Reaction notes

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