Ethyl tert-butyl ether → Hydrogen Peroxide

HRID 1985584Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1985584
[O:1]=[O+:2][O-].[C:4]([O:8][CH2:9]C)([CH3:7])([CH3:6])[CH3:5].[O:11]=[O+][O-].OO>C(OC)(C)(C)C>[CH:9]([O:8][C:4]([CH3:7])([CH3:6])[CH3:5])=[O:11].[OH:1][OH:2]

Komponenten

6

Edukt 3

HCID 12512Ethyl tert-butyl etherHCID 24823Ozone4×HCID 86602708Ozone Hydrogen Peroxide

Produkt 2

HCID 784Hydrogen PeroxideHCID 61207tert-Butyl Formate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 15413tert-Butyl methyl etherLösungsmittel4×

Versuchsvorschrift

Referring to FIG. 12, primary and secondary reactions of MTBE with Ozone are shown. Karpel vel Leitner, R. N., A. L Papailhous, J. P. Crove, J. Payrot, and M. Dore (1994) “Oxidation of Methyl tert-Butyl Ether (MTBE) and Ethyl tert-Butyl Ether (ETBE) by Ozone and Combined Ozone/Hydrogen Peroxide” Ozone Science and Engineering 16, 41-54, described reaction pathways of ozone and MTBE in dilute aqueous solution using controlled experimental conditions. The primary reaction (90% of the consumed mass of MTBE) results in the formation of tert-butyl formate and hydrogen peroxide. A second parallel reaction (less than 10% of the consumed mass of MTBE) generates formaldehyde, TBA, and oxygen.

Quellen und Nachweise

ORD-Eintrag
ord-30a8bffd86224d9a87fcbdb6db2904f4
Quelldatensatz
uspto-grants-2009_06
Patentnummer
US07547388B2

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