HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine hydrate (1:1) → (1S,8R)-5-Cyclopropylmethyl-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | (+)-Camphorquinone | HCID 1549179 | — |
| Reactant | (3-Cyclopropyl-2-oxo-propyl)-phosphonic acid dimethyl ester | HCID 86617460 | — |
| Product | (1S,8R)-5-Cyclopropylmethyl-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene | HCID 69063534 | — |
Reaction Steps
Yellow solid. MS (ESI): 243.2 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, [(3-cyclopropyl-2-oxo-propyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07547697B2 |
| Source dataset | uspto-grants-2009_06 |
| ORD ID | ord-1c1f4f70cbc646d8a54a41eedf6f116c |
| Source note | uspto-grants-2009_06 |