HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine hydrate (1:1) → (1S,8R)-5-(3,3-Dimethyl-butyl)-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | (+)-Camphorquinone | HCID 1549179 | — |
| Reactant | (5,5-Dimethyl-2-oxo-hexyl)-phosphonic acid dimethyl ester | HCID 86617461 | — |
| Product | (1S,8R)-5-(3,3-Dimethyl-butyl)-1,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene | HCID 69070145 | — |
Reaction Steps
light yellow viscous oil MS (ESI): 273.2 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, (5,5-dimethyl-2-oxo-hexyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07547697B2 |
| Source dataset | uspto-grants-2009_06 |
| ORD ID | ord-addcbf5ac5b24096920e55dda3ac5478 |
| Source note | uspto-grants-2009_06 |