HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphonic acid, dimethyl ester → (1SR,8RS)-5-tert-Butyl-11,11-dimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2.4.6-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphonic acid, dimethyl ester | HCID 13361 | — |
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | 7,7-Dimethylbicyclo[2.2.1]heptane-2,3-dione | HCID 3802402 | — |
| Product | (1SR,8RS)-5-tert-Butyl-11,11-dimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2.4.6-triene | HCID 69059876 | — |
Reaction Steps
white solid MS (ESI): 231 (MH+). Prepared from 7,7-dimethyl-bicyclo[2.2.1]heptane-2,3-dione (Childs, Ronald F.; Rogerson, Carol V.; J. Am. Chem. Soc.; EN; 102; 12; 1980; 4159), 3,3-dimethyl-2-oxo-butyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07547697B2 |
| Source dataset | uspto-grants-2009_06 |
| ORD ID | ord-e8c56b1d43a742be855d6d4ab8792242 |
| Source note | uspto-grants-2009_06 |