HRID1986030

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(=O)c1cccc(C(C)=Nc2c(C)cc(C)cc2C)n1

HCID22134468

未命名化合物

HCID57721394

未命名化合物

PRODUCTS

生成物

结构：CCCOc1c(-c2ccccc2)cc(N=C(C)c2cccc(C(C)=Nc3c(C)cc(C)cc3C)n2)cc1-c1ccccc1

HCID57721389

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

2-[1-(2,4,6-trimethylphenylimino)ethyl]-6-acetylpyridine (387 mg, 1.38 mmol) and 4-propoxy-3,5-diphenylaniline (440 mg, 1.45 mmol) were dissolved in 50 ml of toluene. To this solution, 4 Å molecular sieves were added. After standing for 1 day the mixture was filtered. The solvent was removed in vacuo. The residue was crystallised from cold ethanol. The product was isolated as a yellow treacle (700 mg) and used as such.

WORKUP

后处理

additionTo this solution, 4 Å molecular sieves were added
filtrationthe mixture was filtered
customThe solvent was removed in vacuo
customThe residue was crystallised from cold ethanol
customThe product was isolated as a yellow treacle (700 mg)

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2f7de993004e430abc3ae46f38292b32
来源数据集: uspto-grants-2009_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07547783B2
来源说明: uspto-grants-2009_06

反应 SMILES

[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[C:4]([CH3:9])[C:3]=1[N:10]=[C:11]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([C:19](=O)[CH3:20])[N:14]=1)[CH3:12].[CH2:22]([O:25][C:26]1[C:32]([C:33]2[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=2)=[CH:31][C:29]([NH2:30])=[CH:28][C:27]=1[C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)[CH2:23][CH3:24]>C1(C)C=CC=CC=1>[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[C:4]([CH3:9])[C:3]=1[N:10]=[C:11]([C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([C:19](=[N:30][C:29]2[CH:28]=[C:27]([C:39]3[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=3)[C:26]([O:25][CH2:22][CH2:23][CH3:24])=[C:32]([C:33]3[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=3)[CH:31]=2)[CH3:20])[N:14]=1)[CH3:12]