Acetone → 2-Hydroxy-6-methoxy-3,3,14-trimethyl-2,3-dihydro-1H-benzo[b]-chromeno[6,5-g][1,8]naphthyridin-1,7(14H)-dione

HRID 199000Notes

Reaction equation

HRID 199000 reaction equation
[CH3:36][C:37](=[O:38])[CH3:39].[CH3:7][O:8][c:9]1[cH:10][c:11]2[c:16]([c:17]3[c:18]1[c:19](=[O:32])[c:20]1[cH:21][c:22]4[c:23]([n:24][c:25]1[n:26]3[CH3:27])[cH:28][cH:29][cH:30][cH:31]4)[CH:15]=[CH:14][C:13]([CH3:33])([CH3:34])[O:12]2.[K+:6].[Mn:1](=[O:2])([O-:3])(=[O:4])=[O:5].[OH2:35]>>[O:2]=[C:15]1[CH:14]([OH:35])[C:13]([CH3:33])([CH3:34])[O:12][c:11]2[cH:10][c:9]([O:8][CH3:7])[c:18]3[c:17]([c:16]21)[n:26]([CH3:27])[c:25]1[c:20]([c:19]3=[O:32])[cH:21][c:22]2[c:23]([n:24]1)[cH:28][cH:29][cH:30][cH:31]2

Participants

6

Reactant 5

HCID 180AcetoneHCID 813Potassium CationHCID 962WaterHCID 24401PermanganateHCID 68586536HCID 68586536, compound

Product 1

HCID 685855762-Hydroxy-6-methoxy-3,3,14-trimethyl-2,3-dihydro-1H-benzo[b]-chromeno[6,5-g][1,8]naphthyridin-1,7(14H)-dione

Sources & evidence

ORD record
ord-cc0a8d9e646341c19f7d4bd9f5daac79
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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