HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic acid, 2-(triphenylphosphoranylidene)-, methyl ester → HCID 58683735, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic acid, 2-(triphenylphosphoranylidene)-, methyl ester | HCID 17453 | — |
| Reactant | HCID 58683693 | HCID 58683693 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 58683735 | HCID 58683735 | — |
Reaction Steps
7-Nitroquinoline-6-carbaldehyde (370 mg; 1.83 mmol) in toluene (10 ml) was treated with (methoxycarbonylmethylen)triphenylphosphoran (672 mg; 2.0 mmol) for 1 h at reflux temperature. The pure title compound crystallised after cooling the reaction mixture and adding TBME (470 mg; 78%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07645760B2 |
| Source dataset | uspto-grants-2010_01 |
| ORD ID | ord-9b6a56301a2c49a495d7167d430edec3 |
| Source note | uspto-grants-2010_01 |