Tricaprylin → Octanoic Acid

HRID 1992240Notes

Reaction equation

HRID 1992240 reaction equation
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH3:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]([O:30][CH2:31][CH:32]([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])=[O:46])[CH2:33][O:34][C:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[O:36])=[O:29]>>[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH3:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]([O:30][CH2:31][CH:32]([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])=[O:46])[CH2:33][O:34][C:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[O:36])=[O:29]

Participants

5

Reactant 2

HCID 10850TricaprylinHCID 445639Oleic Acid

Product 3

HCID 379Octanoic AcidHCID 10850TricaprylinHCID 445639Oleic Acid

Conditions

Temperature
40 °C

Procedure

230 g of oleic acid (trade name: EXTRA OS-85, produced by NOF Corporation) and 69 g of enzyme powder prepared by Production Example 1 were added to 2070 g of tricaprylin (trade name: Tricaprylin, produced by Sigma Aldrich Japan) in 5000 mL reaction flask. Then, the enzyme reaction was conducted to the mixture stirring with propellers at 40° C. for 13 hours. The surviving enzymes were removed by filtration to obtain 2250 g of the reaction substance. After the reaction, each octanoic acid, oleic acid and tricaprylin was taken out from the reaction substance with a centrifugal molecular distillation equipment (produced by NIPPON SHARYO, LTD.) to obtain 270 g of a triglyceride containing substance.

Workup

  1. customThen, the enzyme reaction
  2. customThe surviving enzymes were removed by filtration
  3. customto obtain 2250 g of the reaction substance
  4. customAfter the reaction

Sources & evidence

ORD record
ord-b830b73b002542999df4fae232ee72cc
Source dataset
uspto-grants-2010_01
Patent number
US07648724B2

Reaction notes

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