Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | Boron tribromide | HCID 25134 | — |
| Reactant | HCID 86616678 | HCID 86616678 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 11540051 | HCID 11540051 | — |
Reaction Steps
A stirring solution of 286 (0.30 g, 0.62 mmol) in CH2Cl2 (10 mL) was chilled to −20° C. under N2 and BBr3, 1 M in CH2Cl2 (2.86, 2.86 mmol, 1 M), was added drop wise. The resulting orange-brown reaction was stirred at −20° C. for 3 h and the reaction then poured onto ice followed by 1 N HCl (20 mL) and EtOAc (100 mL).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07649093B2 |
|---|
| Source dataset | uspto-grants-2010_01 |
|---|
| ORD ID | ord-2d2b18fb84de471dbd2679942396e3ab |
|---|
| Source note | uspto-grants-2010_01 |
|---|
