Potassium Nitrate → HCID 24824867, compound

HRID 1994111Notes

Reaction equation

HRID 1994111 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[NH:11][C:12](=[O:14])[CH3:13])([CH3:4])([CH3:3])[CH3:2].[N+:15]([O-])([O-:17])=[O:16].[K+]>S(=O)(=O)(O)O>[C:1]([C:5]1[CH:10]=[C:9]([N+:15]([O-:17])=[O:16])[CH:8]=[CH:7][C:6]=1[NH:11][C:12](=[O:14])[CH3:13])([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 343805N-(2-tert-butylphenyl)acetamide

Product 1

HCID 24824867HCID 24824867, compound

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Procedure

Concentrated sulfuric acid (30 mL) was cooled to 0° C. and solid N-(2-tert-butylphenyl)acetamide (1.0 g, 5.2 mmol) was added in several portions. To the resulting solution was added KNO3 (578 mg, 5.7 mmol). The reaction mixture was allowed to warm to rt over 2 h and then stirred at rt overnight. The reaction mixture was poured over ice and a white precipitate formed. The precipitate was isolated by filtration (1.04 g, 84%). LCMS: (FA) ES+ 237.2 (M+1), ES− 235.1 (M−1).

Workup

  1. additionThe reaction mixture was poured over ice
  2. customa white precipitate formed
  3. customThe precipitate was isolated by filtration (1.04 g, 84%)

Sources & evidence

ORD record
ord-01eb5ef103504d80a08b7eaaf64a4e16
Source dataset
uspto-grants-2010_01
Patent number
US07652041B2

Reaction notes

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