Toluene → HCID 86623820, compound

Participants

Reaction Conditions

Reaction Steps

121.9 g of 3-bromo-1,1′-biadamantane (349 mmol), 9.58 g of 1,3-dihydroxybenzene (87.0 mmol), 25 mL of toluene and a stirrer were charged in a 300 mL recovery flask. The mixture was heated and agitated at 130° C. for 24 hours under nitrogen flow. A solid was obtained by removing a solvent under reduced pressure. The obtained solid was purified by column chromatography, thus obtaining 37.4 g of 4,6-di[3-(1-adamantyl)-(1-adamantyl)]-1,3-dihydroxybenzene (57.8 mmol; the yield was 66.4%).

Provenance & Evidence