HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → 3'-(Bromomethyl)-2-fluoro-1,1'-biphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2-Fluoro-3'-methyl-1,1'-biphenyl | HCID 12853041 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 3'-(Bromomethyl)-2-fluoro-1,1'-biphenyl | HCID 12853042 | 81.7% |
Reaction Steps
A mixture of 2'-fluoro-3-methyl[1,1'-biphenyl] (1.1 g, 0.006 mole) and N-bromosuccinimide (1.1 g, 0.006 mole) in 11 ml of carbon tetrachloride was irradiated with white light to afford 3-bromomethyl-2'-fluoro[1,1'-biphenyl] (1.3 g). The nmr spectrum was consistent with that expected for the named compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04402973 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-6cd6f418a9964e018af6e32ce4c61665 |
| Source note | uspto-grants-1983_09 |