HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → 3-(Bromomethyl)-3'-chloro-1,1'-biphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 3-Chloro-3'-methyl-1,1'-biphenyl | HCID 2757674 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 3-(Bromomethyl)-3'-chloro-1,1'-biphenyl | HCID 15588649 | 93.4% |
Reaction Steps
3'-Chloro-3-methyl[1,1'-biphenyl] (7.0 g, 0.035 mole) and N-bromosuccinimide (6.4 g, 0.035 mole) in 100 ml of carbon tetrachloride were irradiated for 4 hours with white light to afford 3-bromomethyl-3'-chloro[1,1'-biphenyl] (9.2 g). The nmr spectrum was consistent with that expected for the named compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04402973 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-44f52834545742a5b677624140f0c454 |
| Source note | uspto-grants-1983_09 |