HCID 20065758, compound → (5-Methyl-2-sulfanylidene-2,3-dihydro-1H-imidazol-4-yl)(phenyl)methanone

HRID 1995721Notes

Reaction equation

HRID 1995721 reaction equation
C(C1NC(=S)NC=1C(=O)C1C=CN=CC=1)CC.[CH2:18]([C:20]1[NH:21][C:22](=[S:36])[NH:23][C:24]=1[C:25](=[O:35])[C:26]1[CH:31]=[CH:30][CH:29]=[C:28]2OCO[C:27]=12)C>>[CH3:18][C:20]1[NH:21][C:22](=[S:36])[NH:23][C:24]=1[C:25](=[O:35])[C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1

Participants

3

Reactant 2

HCID 20065758HCID 20065758, compoundHCID 20487488HCID 20487488, compound

Product 1

HCID 13208198(5-Methyl-2-sulfanylidene-2,3-dihydro-1H-imidazol-4-yl)(phenyl)methanone

Procedure

In a like manner, but substituting 2-amino-1-(2,3-methylenedioxyphenyl)-1,3-pentadione; 2-amino-4-methyl-1-[2-(1H-pyrryl)]-1,3-pentadione; or 2-amino-1-(4-pyridyl)-1,3-hexadione for 2-amino-1-phenyl-1-3-butadione in the above example, results in 1,3-dihydro-4-ethyl-5-(2,3-methylenedioxybenzoyl)-2H-imidazole-2-thione; 1,3-dihydro-4-isopropyl-5-[2-(1H-pyrrolyl]-2H-imidazole-2-thione; or 1,3-dihydro-4-propyl-5-isonicotinoyl-2H-imidazole-2-thione, respectively.

Sources & evidence

ORD record
ord-ff87dd5e6f7c4f5d97fbe09af06b0e15
Source dataset
uspto-grants-1983_09
Patent number
US04405628

Reaction notes

Loading…