Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Glycidol | HCID 11164 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 2,2-Diethyl-7,7,9,9-tetramethyl-1-oxa-3,8-diazaspiro(4.5)decan-4-one | HCID 6454848 | — |
| Catalyst | Hydrochloric Acid | HCID 313 | — |
| Catalyst | Trioctylmethylammonium chloride | HCID 21218 | — |
| Solvent | 1-Propanol | HCID 1031 | — |
| Product | HCID 20487774 | HCID 20487774 | — |
Reaction Steps
13.4 g (1/20 mole) of 7,7,9,9-tetramethyl-2,2-diethyl-1-oxa-3,8-diaza-spiro[4.5]decan-4-one, 3.7 g (1/20 mole) of glycidol and 1 drop of concentrated HCl in 60 ml of propanol were stirred for 10 hours at 80° C. A further 3.7 g of glycidol, 0.2 g of tricaprylmethylammonium chloride and 0.3 g of 50% strength NaOH were then added, after which the mixture was stirred for a further 15 hours at 80° C. The mixture was then filtered and the filtrate evaporated to dryness.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04405735 |
|---|
| Source dataset | uspto-grants-1983_09 |
|---|
| ORD ID | ord-53cdd195f6b64246b63766b3cee10575 |
|---|
| Source note | uspto-grants-1983_09 |
|---|
