Carbon Tetrachloride → 1,1,1-Trichloroethane

HRID 1995731Notes

Reaction equation

HRID 1995731 reaction equation
O(Cl)Cl.[Cl:4][CH2:5][CH3:6].[C:7]([Cl:11])(Cl)([Cl:9])[Cl:8]>>[Cl:4][CH:5]([Cl:8])[CH3:6].[Cl:8][C:7]([Cl:11])([Cl:9])[CH3:5]

Participants

5

Reactant 3

HCID 5943Carbon TetrachlorideHCID 6337ChloroethaneHCID 24646Chlorine monoxide

Product 2

HCID 62781,1,1-TrichloroethaneHCID 63651,1-Dichloroethane

Procedure

Kochanny et al., in U.S. Pat. No. 3,872,176, disclose reaction of Cl2O with 1-chloroethane alone or in CCl4 at 0° to 40° C. to give predominantly 1,1-dichloroethane and 1,1,1-trichloroethane;

Sources & evidence

ORD record
ord-70bf83fcc3f94a86bd4bf77e8e9b803d
Source dataset
uspto-grants-1983_09
Patent number
US04405760

Reaction notes

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