HCID 12822120, compound → HCID 54253370, compound

HRID 1995747Notes

Reaction equation

HRID 1995747 reaction equation
C([O:3][CH:4]1[CH:9]([CH:10](OCC)[C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:17])[CH2:8][CH2:7][CH:6](OCC)[O:5]1)C.C(OC1C(C(OCC)C2C=CC(OC)=CC=2)CCC(OCC)O1)C>>[Cl:17][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][C:11]=1[CH:10]=[C:9]([CH2:8][CH2:7][CH:6]=[O:5])[CH:4]=[O:3]

Participants

3

Reactant 2

HCID 12822120HCID 12822120, compoundHCID 12822121HCID 12822121, compound

Product 1

HCID 54253370HCID 54253370, compoundYield 57%

Procedure

Following a procedure analagous to that of Example 1(b) but using respectively 2,6-diethoxy-3-(α-ethoxy-2-chlorobenzyl)tetrahydropyran and 2,6-diethoxy-3-(α-ethoxy-4-methoxybenzyl)tetrahydropyran there was obtained respectively 2-(2-chlorobenzylidene)glutaraldehyde, b.p. 155° C. (0.8 mm), yield: 57%; and 2-(4-methoxybenzylidene)glutaraldehyde, b.p. 175° C. (1.0 mm), yield 61%.

Sources & evidence

ORD record
ord-3d3a8c10df574830a0ad97bd7fd5be05
Source dataset
uspto-grants-1983_09
Patent number
US04405795

Reaction notes

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