{4-[(Undecyloxy)methyl]phenyl}methanol → 4-[(Undecyloxy)methyl]benzaldehyde

HRID 1995778Notes

Reaction equation

HRID 1995778 reaction equation
[CH2:1]([O:12][CH2:13][C:14]1[CH:21]=[CH:20][C:17]([CH2:18][OH:19])=[CH:16][CH:15]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>C(Cl)Cl>[CH2:1]([O:12][CH2:13][C:14]1[CH:15]=[CH:16][C:17]([CH:18]=[O:19])=[CH:20][CH:21]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 2

HCID 53860858{4-[(Undecyloxy)methyl]phenyl}methanolHCID 178418287HCID 178418287, compound

Product 1

HCID 204880034-[(Undecyloxy)methyl]benzaldehyde

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

p-(n-Undecyloxymethyl)benzyl alcohol (10 mmoles) is dissolved in methylene chloride and treated with pyridinium chlorochromate (12 mmoles) at room temperature. When the reaction ceases, the reaction mixture is filtered through a pad of silica gel. The solvent is evaporated from this filtrate to afford the product, p-(n-undecyloxymethyl)benzaldehyde.

Workup

  1. customWhen the reaction ceases
  2. filtrationthe reaction mixture is filtered through a pad of silica gel
  3. customThe solvent is evaporated from this filtrate

Sources & evidence

ORD record
ord-c3ff4db647464e1d9a43e4bc6eb3dfcb
Source dataset
uspto-grants-1983_09
Patent number
US04405810

Reaction notes

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