HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylene Glycol → HCID 20399662, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylene Glycol | HCID 174 | — |
| Reactant | 1,1-Dichloroethane | HCID 6365 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2,2-Dichloro-N-(2-oxopropyl)acetamide | HCID 13233123 | — |
| Catalyst | 2-Naphthalenesulfonic acid | HCID 8420 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 20399662 | HCID 20399662 | 34.4% |
Reaction Steps
Six g of 3-(dichloroacetylamino)-2-propanone (0.03 mole), 2.0 g (0.03 mole) of ethylene glycol, 0.2 g of β-naphthalene sulfonic acid, and 100 ml of dichloroethane were combined in a reaction flask and refluxed until water stopped coming off. Then the reaction was stirred with potassium carbonate and filtered over Florisil. The filtrate was evaporated to yield 2.0 g of 2-methyl-2-(chloroacetylamino)methyl-1,3-dioxolane, a white solid. m.p.=128°-130° C. Structue was confirmed by NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04406686 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-f4026a8c545d42e485be7ecb5c49bcf3 |
| Source note | uspto-grants-1983_09 |