Sodium Carbonate → HCID 13229029, compound

HRID 1995907Notes

Reaction equation

HRID 1995907 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5]/[CH:6]=[C:7](\[NH:11][C:12]([CH:14]1[CH2:16][C:15]1([CH3:18])[CH3:17])=[O:13])/[C:8]([OH:10])=[O:9].[SH:19][C:20]1[N:28]=[CH:27][CH:26]=[CH:25][C:21]=1[C:22]([OH:24])=[O:23].C([O-])([O-])=O.[Na+].[Na+]>O>[C:22]([C:21]1[C:20]([S:19][CH2:2][CH2:3][CH2:4][CH2:5]/[CH:6]=[C:7](\[NH:11][C:12]([CH:14]2[CH2:16][C:15]2([CH3:18])[CH3:17])=[O:13])/[C:8]([OH:10])=[O:9])=[N:28][CH:27]=[CH:26][CH:25]=1)([OH:24])=[O:23]

Participants

5

Reactant 3

HCID 10340Sodium CarbonateHCID 13229022HCID 13229022, compoundHCID 178524460HCID 178524460, compound

Product 1

HCID 13229029HCID 13229029, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 600.0 mg (1.89 mmole) of (+) Z-7-bromo-2-(2,2-dimethylcyclopropanecarboxamido)-2-heptenoic acid, 267.0 mg (1.72 mmole) of 2-mercaptonicotinic acid and 400.6 mg (3.78 mmole) of Na2CO3 in 3.0 ml of H2O was stirred under N2 at room temperature.

Sources & evidence

ORD record
ord-4a17418d67f54ed58e14214076602ac4
Source dataset
uspto-grants-1983_09
Patent number
US04406902

Reaction notes

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