2,4-Difluoronitrobenzene → HCID 58459238, compound

Participants

Reaction Steps

Prepared according to Step D1 in General Procedure D using 2,4-difluoronitro-benzene (3.46 mL, 31.5 mmol) and 2-(methylthio)aniline (3.88 mL, 31.5 mmol) to give 5-fluoro-N-(2-(methylthio)phenyl)-2-nitroaniline as an orange solid: 1H NMR] (400 MHz, DMSO-d6) δ ppm 9.52 (1H, s), 8.26 (1H, dd, J=9.4, 6.1 Hz), 7.34-7.45 (3H, m), 7.26-7.32 (1H, m), 6.67-6.75 (1H, m), 6.35 (1H, dd, J=11.6, 2.6 Hz), 2.43 (3H, s); LC-MS (ESI) m/z 279.0 [M+H]+ at 2.176 min; m/z 277.0 [M−H]− at 2.169 min.

Provenance & Evidence