化工社化工社 化学情報印刷レポート · 研究参考用
Pentanal → 2-Methylbutanal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pentanal | HCID 8063 | — |
| 反応物 | 2-Propylhept-2-enal | HCID 118745 | — |
| 生成物 | 2-Methylbutanal | HCID 7284 | — |
| 生成物 | Pentanal | HCID 8063 | — |
| 生成物 | 2-Propyl-4-methylhexenal | HCID 3018738 | — |
反応手順
This example describes the process according to the invention for the aldol condensation of n-pentanal (n-valeraldehyde) to 2-propylheptenal (1+1 product), and the co-aldolization of n-pentanal with 2-methylbutanal to give the cross-product (1+2 product), 2-propyl-4-methylhexenal. The reactor used was, as in Example 3, a DN15 tube (internal diameter 17.3 mm) of length 4 m with a total volume of 9.11. About 50% of the total volume of the tubular reactor was filled with static mixers. In contrast to Example 3, the C5-aldehyde mixture reactant was not fed in upstream of the reactor, but instead into the NaOH circulation system upstream of the circulation pump according to FIG. 2.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08581008B2 |
| 出典データセット | uspto-grants-2013_11 |
| ORD ID | ord-363eaafd1f384ddaab6df80212889b34 |
| 出典メモ | uspto-grants-2013_11 |