HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → HCID 67171199, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | Cyclopent-2-en-1-one-ethyleneacetal | HCID 69668 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 67171199 | HCID 67171199 | — |
Reaction Steps
A mixture of 1,4-dioxaspiro[4.4]non-6-ene (5 g), methyl acrylate (10.24 g), and hydroquinone (0.13 g) was heated in an autoclave at 100° C. in acetonitrile (12 mL) for three days. After cooling, the solvent was removed, and residue was purified by flash chromatography on silica gel eluting with 4:1 hexane/ethyl acetate to give the title compound as a mixture of two 5-isomers.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08586754B2 |
| Source dataset | uspto-grants-2013_11 |
| ORD ID | ord-9a83b6c32e944354a096039e4e4b25c1 |
| Source note | uspto-grants-2013_11 |