HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → Tris(dimethylaminomethyl)phosphine trihydrochloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | N,N',N''-[Phosphanetriyltris(methylene)]tris(N-methylmethanamine) | HCID 12717838 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | Tris(dimethylaminomethyl)phosphine trihydrochloride | HCID 12717839 | 100.3% |
Reaction Steps
A rubber-capped serum bottle containing 25 ml of ethanol was purged of air with argon, and then charged by means of a syringe with 2.31 g (11.25 mmol) of tris(dimethylaminomethyl)phosphine and 7.00 ml (42.0 mmol) of 6N hydrochloric acid. The solution, which fumed but remained clear, was shaken for 30 min and then stripped under vacuum, leaving 3.55 g (100% yield) of tris(dimethylaminomethyl)phosphine trihydrochloride as a white, crystalline solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04196149 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-b85e35f3dc4c4d189446de7c5d628789 |
| Source note | uspto-grants-1980_04 |