HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloroacetyl chloride → 2,2-Dichloro-1-[2-(dichloromethyl)-1,3-oxazolidin-3-yl]ethan-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloroacetyl chloride | HCID 6593 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | HCID 20344667 | HCID 20344667 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 2,2-Dichloro-1-[2-(dichloromethyl)-1,3-oxazolidin-3-yl]ethan-1-one | HCID 20344678 | 98.4% |
Reaction Steps
2nd part: By operating as in the second part of Example 13, but using 23.5 g (0.15 mole) of 2-dichloromethyl-1,3-oxazolidine, 18 g (0.18 mole) of triethylamine and 24.3 g (0.165 mole) of dichloroacetyl chloride in 200 ml of chloroform, after the removal of the chloroform by distillation under vacuum, 39.4 g (yield 98%) of crude 2-dichloromethyl-3-dichloroacetyl-1,3-oxazolidine is obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04197110 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-914523dca7c74637b9436b0c8d1a6e1e |
| Source note | uspto-grants-1980_04 |