3-Chloro-2-methylaniline → HCID 23333896, compound

HRID 2049536Notes

Reaction equation

HRID 2049536 reaction equation
[CH3:1][C:2]1[C:8]([Cl:9])=[CH:7][CH:6]=[CH:5][C:3]=1[NH2:4].[C:10]([C:13]1[CH:20]=[CH:19][C:16]([CH:17]=O)=[CH:15][CH:14]=1)([OH:12])=[O:11]>>[C:10]([C:13]1[CH:20]=[CH:19][C:16]([CH:17]=[N:4][C:3]2[CH:5]=[CH:6][CH:7]=[C:8]([Cl:9])[C:2]=2[CH3:1])=[CH:15][CH:14]=1)([OH:12])=[O:11]

Participants

3

Reactant 2

HCID 68943-Chloro-2-methylanilineHCID 120884-Formylbenzoic acid

Product 1

HCID 23333896HCID 23333896, compound

Procedure

2-methyl-3-chloroaniline (0.25 moles) and p-carboxybenzaldehyde (0.25 moles) were ground in a mortar. The mixture was heated, with stirring in a water bath for 1.5 hours. Distillation at reduced pressure gave N-(p-carboxybenzylidene)-2-methyl-3-chloroaniline as a second fraction.

Workup

  1. temperatureThe mixture was heated
  2. distillationDistillation at reduced pressure

Sources & evidence

ORD record
ord-ff9c0103a30d422fb17c7955ebc10a7d
Source dataset
uspto-grants-1980_04
Patent number
US04198349

Reaction notes

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