Ethanol → HCID 20344096, compound

HRID 2049628Notes

Reaction equation

HRID 2049628 reaction equation
[F:1][C:2]1[CH:3]=[C:4]([CH:15]=[CH:16][CH:17]=1)[O:5][C:6]1[CH:14]=[CH:13][CH:12]=[CH:11][C:7]=1[C:8]([OH:10])=[O:9].OS(O)(=O)=O.[CH2:23](O)[CH3:24]>>[F:1][C:2]1[CH:3]=[C:4]([CH:15]=[CH:16][CH:17]=1)[O:5][C:6]1[CH:14]=[CH:13][CH:12]=[CH:11][C:7]=1[C:8]([O:10][CH2:23][CH3:24])=[O:9]

Participants

4

Reactant 3

HCID 702EthanolHCID 1118Sulfuric AcidHCID 20344099HCID 20344099, compound

Product 1

HCID 20344096HCID 20344096, compound

Procedure

2-(3-Fluorophenoxy)benzoic acid (10 g.) and 100 ml of ethanol containing 1 ml. of concentrated H2SO4 were heated at reflux through molecular sieves overnight. The solvent was evaporated, and the residue poured into 50 ml. of 7% NaHCO3. The resulting ester was extracted with ether. ##STR10##

Workup

  1. temperatureat reflux through molecular sieves overnight
  2. customThe solvent was evaporated
  3. additionthe residue poured into 50 ml
  4. extractionThe resulting ester was extracted with ether

Sources & evidence

ORD record
ord-34832fdf8e0e476fa5110ec0262fc185
Source dataset
uspto-grants-1980_04
Patent number
US04198421

Reaction notes

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