Thiocyanic acid, chloromethyl ester → HCID 54108257, compound

HRID 2049671Notes

Reaction equation

HRID 2049671 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][CH:8]=[CH:7][C:3]=1[C:4]([OH:6])=[S:5].Cl[CH2:12][S:13][C:14]#[N:15]>>[S:13]([CH2:12][O:6][C:4](=[S:5])[C:3]1[CH:7]=[CH:8][CH:9]=[CH:10][C:2]=1[Cl:1])[C:14]#[N:15]

Participants

3

Reactant 2

HCID 76755Thiocyanic acid, chloromethyl esterHCID 178526133HCID 178526133, compound

Product 1

HCID 54108257HCID 54108257, compoundYield 77%

Procedure

28.5 g (0.14 mol) of the K salt of 2-chloro-thiobenzoic acid and 15 g (0.14 mol) of chloromethyl thiocyanate were reacted and processed as in Example 1 B. 26.3 g of a yellowish oil having a density of 1.36 (this corresponds to a yield of 77% of the theoretical conversion).

Sources & evidence

ORD record
ord-807c2b899f35411797801c6978b9d811
Source dataset
uspto-grants-1980_04
Patent number
US04198428

Reaction notes

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