Thiocyanic acid, chloromethyl ester → HCID 54006760, compound

HRID 2049674Notes

Reaction equation

HRID 2049674 reaction equation
[Cl:1][C:2]1[CH:10]=[C:9]([Cl:11])[CH:8]=[CH:7][C:3]=1[C:4]([OH:6])=[S:5].Cl[CH2:13][S:14][C:15]#[N:16]>>[S:14]([CH2:13][O:6][C:4](=[S:5])[C:3]1[CH:7]=[CH:8][C:9]([Cl:11])=[CH:10][C:2]=1[Cl:1])[C:15]#[N:16]

Participants

3

Reactant 2

HCID 76755Thiocyanic acid, chloromethyl esterHCID 178526138HCID 178526138, compound

Product 1

HCID 54006760HCID 54006760, compoundYield 81%

Procedure

15.8 g (0.064 mol) of the K salt of 2,4-dichloro-thiobenzoic acid and 6.3 g (0.06 mol) of chloromethyl thiocyanate were reacted and processed as in Example 1 B. 13.5 g of a yellowish oil having a density of 1.45 (this corresponds to a yield of 81% of the theoretical conversion). Use Examples

Sources & evidence

ORD record
ord-c85a8c2840fb457b98b3da29ee0c861d
Source dataset
uspto-grants-1980_04
Patent number
US04198428

Reaction notes

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