Ethyl bromoacetate → HCID 53696458, compound

HRID 2049703Notes

Reaction equation

HRID 2049703 reaction equation
[CH3:1][C:2](=[CH:6][CH:7]=[CH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3](=[O:5])[CH3:4].Br[CH2:16][C:17]([O:19][CH2:20][CH3:21])=[O:18]>[Zn]>[OH:5][C:3]([CH3:4])([C:2]([CH3:1])=[CH:6][CH:7]=[CH:8][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)[CH2:16][C:17]([O:19][CH2:20][CH3:21])=[O:18]

Participants

4

Reactant 2

HCID 7748Ethyl bromoacetateHCID 868863,5-Hexadien-2-one, 3-methyl-6-phenyl-

Product 1

HCID 53696458HCID 53696458, compound

Reagents, catalysts & solvents 1

HCID 23994ZincCatalyst

Procedure

Using 8.60 g of 3-methyl-6-phenyl-3,5-hexadien-2-one, 8.0 ml of ethyl bromoacetate and 4.60 g of zinc, the reaction and the purification of the product were carried out according to the method described in Example 1 (a) affording 12.20 g of ethyl 3-hydroxy-3,4-dimethyl-7-phenyl-4,6-heptadienoate.

Workup

  1. customthe reaction
  2. customthe purification of the product

Sources & evidence

ORD record
ord-71bc9772872449a8ab684a547d8ebe55
Source dataset
uspto-grants-1980_04
Patent number
US04198425

Reaction notes

Loading…