HCID 20344416, compound → HCID 12593115, compound

HRID 2049755Notes

Reaction equation

HRID 2049755 reaction equation
Cl[C:2]1[N:3]([CH2:13][CH3:14])[C:4](=[O:12])[C:5]2[C:10]([CH:11]=1)=[CH:9][CH:8]=[CH:7][CH:6]=2.[CH3:15][S:16]C.[Na]>>[CH2:13]([N:3]1[C:2]([S:16][CH3:15])=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4]1=[O:12])[CH3:14]

Participants

3

Reactant 2

HCID 20344416HCID 20344416, compoundHCID 86593196Sodium methylsulfide

Product 1

HCID 12593115HCID 12593115, compound

Procedure

By following the same procedure as in Example 1 using 0.6 g. of 3-chloro-2-ethyl-1-oxo-1,2-dihydroisoquinoline and 0.8 g. of an aqueous solution of 20% sodium methylsulfide, 0.31 g. of 2-ethyl-3-methylthio-1-oxo-1,2-dihydroisoquinoline was obtained (recrystallized from cyclohexane).

Sources & evidence

ORD record
ord-d10e2e81edec472eb1ababadcf3974d2
Source dataset
uspto-grants-1980_04
Patent number
US04198512

Reaction notes

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