1-(Bromomethyl)-3-phenoxybenzene → m-Phenoxybenzyl 3-phenylthio-2,2-dimethylcyclopropanecarboxylate

HRID 2049833Notes

Reaction equation

HRID 2049833 reaction equation
[C:1]1([S:7][CH:8]2[CH:10]([C:11]([OH:13])=[O:12])[C:9]2([CH3:15])[CH3:14])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O:16]([C:23]1[CH:24]=[C:25]([CH:28]=[CH:29][CH:30]=1)[CH2:26]Br)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[C:1]1([S:7][CH:8]2[CH:10]([C:11]([O:13][CH2:26][C:25]3[CH:28]=[CH:29][CH:30]=[C:23]([O:16][C:17]4[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=4)[CH:24]=3)=[O:12])[C:9]2([CH3:15])[CH3:14])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

3

Reactant 2

HCID 945441-(Bromomethyl)-3-phenoxybenzeneHCID 203049443-Phenylthio-2,2-dimethylcyclopropanecarboxylic acid

Product 1

HCID 20344545m-Phenoxybenzyl 3-phenylthio-2,2-dimethylcyclopropanecarboxylate

Procedure

Using the method of Example 3, the above product is hydrolyzed to 3-phenylthio-2,2-dimethylcyclopropanecarboxylic acid, which is then reacted with m-phenoxybenzyl bromide to yield m-phenoxybenzyl 3-phenylthio-2,2-dimethylcyclopropanecarboxylate.

Sources & evidence

ORD record
ord-5ed73a76ad124c45ae3573fbaadbf015
Source dataset
uspto-grants-1980_04
Patent number
US04198527

Reaction notes

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