HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiophenol → Methyl 3-phenylthio-2-propenoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiophenol | HCID 7969 | — |
| Reactant | Methyl propiolate | HCID 13536 | — |
| Catalyst | Triethylamine | HCID 8471 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Methyl 3-phenylthio-2-propenoate | HCID 54247095 | — |
Reaction Steps
A solution of 2.45 g (24.54 mmol) methyl propiolate and 20 ml ether is treated with 2.7 g (24.54 mmol) benzenethiol with 4 drops triethylamine in 25 ml ether over 15 min at 20°. After stirring for 24 hr, the reaction mixture is rotoevaporated to yield methyl 3-phenylthio-2-propenoate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04198527 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-8d34b6ab10a649caa33a48bc7b6d3b35 |
| Source note | uspto-grants-1980_04 |