HCID 20344522, compound → HCID 20344564, compound

HRID 2049841Notes

Reaction equation

HRID 2049841 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH:9]=[CH:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])=[CH:4][CH:3]=1.C1([Hg][C:23](Br)([Br:25])[F:24])C=CC=CC=1>>[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH:9]2[CH:10]([C:11]([O:13][CH2:14][CH3:15])=[O:12])[C:23]2([Br:25])[F:24])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 20344522HCID 20344522, compoundHCID 54166829HCID 54166829, compound

Product 1

HCID 20344564HCID 20344564, compound

Procedure

Ethyl 3-(4-fluorophenylthio)-2-propenoate can also be combined with phenyl(dibromofluoromethyl)mercury, in 1:1 ratio, and heated at 80°, with stirring for 30 min, to give ethyl 3-(4-fluorophenylthio)-2-bromo-2-fluorocyclopropanecarboxylate.

Workup

  1. temperatureheated at 80°

Sources & evidence

ORD record
ord-97bb76f5d238435c84f2616e91e98a5f
Source dataset
uspto-grants-1980_04
Patent number
US04198527

Reaction notes

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