HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2050034Generated: November 2, 2026
2,3-Dimethyl-1,3-butadiene → HCID 12477039, compound
https://huagongshe.com/reaction/2050034
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2,3-Dimethyl-1,3-butadiene | HCID 10566 | — |
| Reactant | 2-Octyl-1H-1lambda~4~,2-thiazole-1,3(2H)-dione | HCID 15960475 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | HCID 12477039 | HCID 12477039 | 51% |
Reaction Steps
To a solution of 2.2 g (0.01 mole) of 2-n-octyl-4-isothiazolin-3-one 1-oxide in 15 ml of ethylene dichloride is added 1.1 g (0.012 mole) of 2,3-dimethyl-1,3-butadiene. The solution is stirred and maintained at 60° C. overnight. The mixture is concentrated to give a dark, thick oil. The oil is further purified by column chromatography (90% benzene, 10% acetone, silica) to yield 1.58 g (51%) of product as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04199591 |
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| Source dataset | uspto-grants-1980_04 |
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| ORD ID | ord-28404ea3b1684924a9bdac79e32e8ccb |
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| Source note | uspto-grants-1980_04 |
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