Carbon Dioxide → HCID 20343289, compound

HRID 2050095Notes

Reaction equation

HRID 2050095 reaction equation
Cl[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]([F:17])([F:16])[F:15])=[CH:9][CH:8]=1)[C:3]([CH3:6])([CH3:5])[CH3:4].[C:18](=[O:20])=[O:19]>>[C:3]([CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]([F:17])([F:16])[F:15])=[CH:9][CH:8]=1)[C:18]([OH:20])=[O:19])([CH3:6])([CH3:5])[CH3:4]

Participants

3

Reactant 2

HCID 280Carbon DioxideHCID 20343343HCID 20343343, compound

Product 1

HCID 20343289HCID 20343289, compound

Procedure

The neopentyl chloride prepared in Example 37 is converted to the Grignard reagent and subsequent carbonation with carbon dioxide according to the procedure of Weinstein and Morse [Journal of the American Chemical Society 74, 1133 (1952)] gives the desired acid as a white solid.

Sources & evidence

ORD record
ord-44186d69548147d2817904b0576eb466
Source dataset
uspto-grants-1980_04
Patent number
US04199595

Reaction notes

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