HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl chloroformate → cis-3-Benzyloxycarbonylamino-4-oxo-2-p-toluenesulfonyloxymethylazetidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl chloroformate | HCID 10387 | — |
| Reactant | Phenoxyacetyl chloride | HCID 69703 | — |
| Reactant | Methyl cis-1-(2,4-dimethoxybenzyl)-3-azido-4-oxoazetidine-2-carboxylate | HCID 86734328 | — |
| Reactant | cis-3-Amino-4-oxo-2-p-toluenesulfonyloxymethylazetidine | HCID 86734334 | — |
| Product | cis-3-Benzyloxycarbonylamino-4-oxo-2-p-toluenesulfonyloxymethylazetidine | HCID 86736961 | — |
Reaction Steps
Reaction of cis-3-amino-4-oxo-2-p-toluenesulfonyloxymethylazetidine with benzyl chloroformate according to the procedure described in Preparation 2 for reaction of methyl cis-3-azido-1-(2,4-dimethoxybenzyl)-4-oxoazetidine-2-carboxylate and phenoxyacetyl chloride gives cis-3-benzyloxycarbonylamino-4-oxo-2-p-toluenesulfonyloxymethylazetidine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04200572 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-fc1b09b81c364fcda19e9b16304d3c16 |
| Source note | uspto-grants-1980_04 |