Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Cinnamoylbenzene | HCID 7189 | — |
| Reactant | 1-Decanol | HCID 8174 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | Nonane | HCID 8141 | 16.1% |
Reaction Steps
In a typical combined dehydrogenation/decarbonylation, 1-decanol (398 μmol) was treated with RuCl2 (PPh3)3 (19 μmol), RhCl(PPh3)3 (96 pmol) and benzalacetophenone (438 pmol) in 2 ml of N-methyl-2-pyrrolidinone and heated under nitrogen at 125° C. After 40 hours, 64 μmol of nonane had formed; after 6 days the yield of nonane was 92 μmol (96% based on Rh).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | USH0000918 |
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| Source dataset | uspto-grants-1991_05 |
|---|
| ORD ID | ord-8eea5c4e2ce241da80721c80f1fea3b2 |
|---|
| Source note | uspto-grants-1991_05 |
|---|
