Cesium fluoride → Allyl Oxalofluoride

HRID 2050485Notes

Reaction equation

HRID 2050485 reaction equation
[CH2:1]([O:4][C:5](=[O:9])[C:6](Cl)=[O:7])[CH:2]=[CH2:3].[F-:10].[Cs+]>>[CH2:1]([O:4][C:5](=[O:9])[C:6]([F:10])=[O:7])[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 25953Cesium fluorideHCID 3018516Allyl chlorooxoacetate

Product 1

HCID 14153244Allyl Oxalofluoride

Procedure

By the procedure of the preceding Preparation, allyl oxalochloride (252.5 g, 1.70 mol) and cesium fluoride (284 g, 1.87 mol) were converted to twice distilled title product, b.p. 48°-50° C./35 mm; 124°-126° C. (atmospheric pressure).

Workup

  1. distillationto twice distilled title product, b.p. 48°-50° C./35 mm
  2. custom124°-126° C. (atmospheric pressure)

Sources & evidence

ORD record
ord-5958e7854f444492a46f28fb012376ca
Source dataset
uspto-grants-1991_05
Patent number
US05013729

Reaction notes

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