HRID2050675

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：O=C[C@@H]1[C@@H](OCc2ccccc2)[C@H](O)CCN1C(=O)OCc1ccccc1

HCID131716887

未命名化合物

PRODUCTS

生成物

结构：O=C(OCc1ccccc1)N1CC[C@@H](O)[C@H](OCc2ccccc2)[C@H]1CO

HCID14523446

未命名化合物

PROCEDURE

实验过程

reducing the lactol (24) with sodium borohydride to give a diol (25) from which the protecting groups are removed by hydrogenolysis to give the desired fagomine (3) ##STR17## wherein Bn=CH2Ph and Z=COOCH2Ph.