5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile → HCID 53654257, compound

HRID 2050803Notes

Reaction equation

HRID 2050803 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[OH:18][CH2:19][CH2:20][O:21][N:22]=[C:23]([CH2:25][CH3:26])[CH3:24]>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:18][CH2:19][CH2:20][O:21][N:22]=[C:23]([CH3:24])[CH2:25][CH3:26])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrileHCID 86217928HCID 86217928, compound

Product 1

HCID 53654257HCID 53654257, compound

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and 2-butanone (2-hydroxyethyl) oxime, there is obtained 2-[(1-methylpropylideneamino)oxy]-ethyl 5,7- dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a syrup, mass spectrum m/e: M+ 351 (23), 281 (5), 237 (57), 194 (100), 114 (100), 70 (12);

Sources & evidence

ORD record
ord-78d30317008f48189f71fcf1ad8daf9b
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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