2-Propanone, O-(2-hydroxypropyl)oxime → HCID 19833934, compound

HRID 2050804Notes

Reaction equation

HRID 2050804 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[OH:18][CH:19]([CH3:26])[CH2:20][O:21][N:22]=[C:23]([CH3:25])[CH3:24]>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:18][CH:19]([CH3:26])[CH2:20][O:21][N:22]=[C:23]([CH3:25])[CH3:24])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 152789382-Propanone, O-(2-hydroxypropyl)oximeHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

Product 1

HCID 19833934HCID 19833934, compound

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and acetone (2-hydroxypropyl) oxime, there is obtained 2-[(isopropylideneamino)oxy]-1-methylethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a syrup, mass spectrum m/e: M+ 351 (12), 295 (4), 237 (81), 194 (100), 114 (35), 56 (78);

Sources & evidence

ORD record
ord-e42438c78fe1419897fd4401b6946cd0
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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