2-Naphthalenemethanol → 2-naphthylmethyl 5,7-dihydro-6H-dibenz[c,e]-azepine-6-carboximidate

HRID 2050810Notes

Reaction equation

HRID 2050810 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[OH:18][CH2:19][C:20]1[CH:29]=[CH:28][C:27]2[C:22](=[CH:23][CH:24]=[CH:25][CH:26]=2)[CH:21]=1>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:18][CH2:19][C:20]3[CH:29]=[CH:28][C:27]4[C:22](=[CH:23][CH:24]=[CH:25][CH:26]=4)[CH:21]=3)[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 741282-NaphthalenemethanolHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

Product 1

HCID 198340152-naphthylmethyl 5,7-dihydro-6H-dibenz[c,e]-azepine-6-carboximidate

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and 2-hydroxymethylnaphthalene, there is obtained 2-naphthylmethyl 5,7-dihydro-6H-dibenz[c,e]-azepine-6-carboximidate as a resin, mass spectrum m/e: M+ 378 (19), 237 (15), 194 (90), 141 (100), 115 (53);

Sources & evidence

ORD record
ord-ab1ffe12092c45a3aa82af3f3c1570c2
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

Loading…