Cyclopropanemethanol → HCID 19833944, compound

HRID 2050816Notes

Reaction equation

HRID 2050816 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[OH:18][CH2:19][CH:20]1[CH2:22][CH2:21]1>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:18][CH2:19][CH:20]3[CH2:22][CH2:21]3)[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 75644CyclopropanemethanolHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

Product 1

HCID 19833944HCID 19833944, compound

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and hydroxymethylcyclopropane, there is obtained cyclopropylmethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate, m.p. 80°-83° C., mass spectrum m/e: M+ 292 (2), 237 (80), 194 (100);

Sources & evidence

ORD record
ord-cc0c6497cb25448a9bddf87dcd58912d
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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