Benzoyl chloride → 2-ethoxycarbonylamino-ethyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

HRID 2050825Notes

Reaction equation

HRID 2050825 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:26])[O:17][CH2:18][CH2:19][NH:20][C:21]([O:23][CH2:24][CH3:25])=[O:22])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:27](Cl)(=[O:34])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1>>[C:27]([N:26]=[C:16]([N:7]1[CH2:8][C:9]2[CH:15]=[CH:14][CH:13]=[CH:12][C:10]=2[C:11]2[CH:1]=[CH:2][CH:3]=[CH:4][C:5]=2[CH2:6]1)[O:17][CH2:18][CH2:19][NH:20][C:21]([O:23][CH2:24][CH3:25])=[O:22])(=[O:34])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1

Participants

3

Reactant 2

HCID 7412Benzoyl chlorideHCID 198338992-ethoxycarbonylamino-ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

Product 1

HCID 198338912-ethoxycarbonylamino-ethyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

Procedure

starting from 2-ethoxycarbonylamino-ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate and benzoyl chloride, there is obtained 2-ethoxycarbonylamino-ethyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a resin, mass spectrum m/e: M+ 457 (6), 341 (18), 194 (100), 116 (75), 105 (75);

Sources & evidence

ORD record
ord-237ed056d31a4432956bd479b844eb92
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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