Benzoyl chloride → dodecyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]-azepine-6-thiocarboximidate

HRID 2050826Notes

Reaction equation

HRID 2050826 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]([S:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])=[NH:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:31](Cl)(=[O:38])[C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1>>[C:31]([N:17]=[C:16]([N:7]1[CH2:6][C:5]2[CH:4]=[CH:3][CH:2]=[CH:1][C:11]=2[C:10]2[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=2[CH2:8]1)[S:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])(=[O:38])[C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1

Participants

3

Reactant 2

HCID 7412Benzoyl chlorideHCID 19833911dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate

Product 1

HCID 18645182dodecyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]-azepine-6-thiocarboximidate

Procedure

starting from dodecyl 5,7-dihydro-6H-dibenz[c,e]-azepine-6-thiocarboximidate and benzoyl chloride, there is obtained dodecyl N-benzoyl-5,7-dihydro-6H-dibenz[c,e]-azepine-6-thiocarboximidate as a resin, mass spectrum m/e: M+ 526 (23), 357 (18), 194 (94), 105 (100);

Sources & evidence

ORD record
ord-eaf8f9397e65472aaa1989fa2ead8bc9
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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