4-tert-Butylbenzoyl chloride → ethyl N-(p-tert.butylbenzoyl)-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

HRID 2050851Notes

Reaction equation

HRID 2050851 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:20])[O:17][CH2:18][CH3:19])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:21]([C:25]1[CH:33]=[CH:32][C:28]([C:29](Cl)=[O:30])=[CH:27][CH:26]=1)([CH3:24])([CH3:23])[CH3:22]>>[C:21]([C:25]1[CH:26]=[CH:27][C:28]([C:29]([N:20]=[C:16]([N:7]2[CH2:6][C:5]3[CH:4]=[CH:3][CH:2]=[CH:1][C:11]=3[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8]2)[O:17][CH2:18][CH3:19])=[O:30])=[CH:32][CH:33]=1)([CH3:24])([CH3:22])[CH3:23]

Participants

3

Reactant 2

HCID 743724-tert-Butylbenzoyl chlorideHCID 19833914ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6carboximidate

Product 1

HCID 19833998ethyl N-(p-tert.butylbenzoyl)-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

Procedure

starting from ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate and p-tert.butylbenzoyl chloride, there is obtained ethyl N-(p-tert.butylbenzoyl)-5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a foam, mass spectrum m/e: M+ 426 (8), 398 (6), 194 (100), 161 (36);

Sources & evidence

ORD record
ord-4651c0e9e9194ebcb40c8ba599425097
Source dataset
uspto-grants-1991_05
Patent number
US05015640

Reaction notes

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