Butylamine → HCID 13750865, compound

HRID 2051042Notes

Reaction equation

HRID 2051042 reaction equation
[CH2:1]([NH2:5])[CH2:2][CH2:3][CH3:4].[N+:6]([C:9]1[C:14]([N+]([O-])=O)=[CH:13][C:12]([OH:18])=[C:11]([O:19][CH3:20])[CH:10]=1)([O-:8])=[O:7]>O>[CH2:1]([NH:5][C:14]1[C:9]([N+:6]([O-:8])=[O:7])=[CH:10][C:11]([O:19][CH3:20])=[C:12]([OH:18])[CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 8007ButylamineHCID 184586Phenol, 2-methoxy-4,5-dinitro-

Product 1

HCID 13750865HCID 13750865, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture consisting of 80 ml of n-butylamine, 10 ml of water and 0.1 mol (21.4 g) of 4,5-dinitro-2-methoxyphenol, prepared in Example 2, is heated under reflux. After 4 hours heating, the reaction medium is diluted with 800 g of ice-cold water; the expected product precipitates. After being drained and dried, it is taken up in 300 ml of dilute caustic soda and precipitated by adding acetic acid.

Workup

  1. customprepared in Example 2
  2. temperatureis heated
  3. temperatureunder reflux
  4. temperatureAfter 4 hours heating
  5. customthe expected product precipitates
  6. customdried
  7. customprecipitated
  8. additionby adding acetic acid

Sources & evidence

ORD record
ord-990e5987ee0f463e93beb5292ab2b86e
Source dataset
uspto-grants-1991_05
Patent number
US05015769

Reaction notes

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